Course Contents

Chemical Equilibrium Types of chemical Equilibrium characterization of chemical equilibrium, Law of Mass Action, various types of equilibrium constant relation between Kp. Kc, Kx, Kn le-Chatelier's Principle and its applications. Chemical Kinetics: Introduction to chemical kinetics order, molecularity. nits of rate of reaction, rate law.order reaction, first order reaction, half life, period of first de reaction. (Numericals) Examples of first and reaction, Pseudo first order reaction methods to determine order of reaction.Energy of activation, its determination Assignment Presentation Surface Chemistry: Introduction, Adsorption, Absorption, Chemisorption. Adsorption is athens, Langmuir & Freundlich adsorption isotherms), catalyst catalysis, theories of catalysis Colloidal State: Introduction, classification of colloids, preparations of IV colloids, macromolecules, emulsions, preparation. properties, uses, gels, preparation properties and usesAerosols, surfactants, preparation, Importance of colloids, application in daily life. Exercise Aromatic Hydrocarbons: Differentiate between aliphatic & aromatic hydrocarbons, sources, nomenclature of aromatic hydrocarbons. Structure of Benzene: Kekule Structure, (Static and dynamic), Modem interpretation of structure of benzene. (A) Resonance method (B) Molecular orbital method. Aromaticity. The Huckel rule, synthesis of Benzene, Synthesis of homologues of benzene, physical properties of benzene Reactivity of benzene, electrophilic substitution reactions of benzene, addition reactions of benzene, oxidation reactions, orientation of benzene. Naphthalene: Structure and preparation of naphthalene, reaction of naphthalene, exercise of aromatic hydrocarbons, Revision, assignment or presentation Alkyl Halides: Nomenclature, structure, physical properties, methods of preparation of alkyl halides, reactivity, reaction of alkyl halides Nucleophilic substitution reactions, mechanism of SNI and SN2, kinetic evidence, stereochemical evidence, factors affecting reactivity in substitution reactions Elimination reactions, comparison between SN and E reactions. Hofmann and Saytzeff rules remaining reaction of alkyl halide like reduction, Wurtz reactions Friedel-Crafts reaction, Rearrangement reactions Organometallic Compound: Grignard reagents, formation of grignard reagent, XVI structure and reactivity of Grignard reagent, important synthetic reactions and application of Grignard's reagent. Exercise, assignment or presentation.

Course Synopsis

This course has been designed for students of different disciplines to have basic knowledge about physical and organic chemistry. In the first part they will study Chemical equilibrium, Chemical kinetics , Surface chemistry and colloidal solutions. In Organic part they will study Aromatic hydrocarbons, Alkyl halides, Nucleophilic substitution reactions and elimination reactions.

Course Learning Outcomes

Student will have a firm foundation in the fundamentals and application of physical and organic chemistry theories. From practical work they will be able to carry out chemical experiments as well as accurately record and analyze results of experiments.